MATERIAL SAFETY DATA SHEET
EQUILON MSDS: 66501E-03 01/04/99
DIESELMOTIVE 494
TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS
EQUILON ENTERPRISES LLC
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
_______________________________________________________________________________
SECTION I NAME
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PRODUCT: DIESELMOTIVE 494
CHEM NAME: MIXTURE (SEE SECTION II-A)
CHEM FAMILY: PETROLEUM HYDROCARBON; DIESEL ENGINE OIL
SHELL CODE: 54748
HEALTH HAZARD: 1 FIRE HAZARD: 1 REACTIVITY: 0
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SECTION II-A PRODUCT/INGREDIENT
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NO. COMPOSITION CAS NO. PERCENT
--- ----------- ------- -------
P DIESELMOTIVE 494
1 HYDROTREATED HEAVY NAPHTHENIC DISTILLATE 64742-52-5 50-60
2 ACID TREATED HEAVY NAPHTHENIC DISTILLATE 64742-18-3 20-30
3 HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 5-10
4 ADDITIVES MIXTURE 10-15
5 CHLORINATED PARAFFIN 63449-39-8 <1
NFPA HAZARD RATING: HEALTH 0 FIRE 1 REACTIVITY 0
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SECTION II-B ACUTE TOXICITY DATA
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NO. ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50
--- --------------- ----------------- ---------------------
P NOT AVAILABLE
1 >5.0 G/KG, RAT* >5.0 G/KG, RABBIT* NOT AVAILABLE
2 >5.0 G/KG, RAT* >5.0 G/KG, RABBIT* NOT AVAILABLE
3 >5.0 G/KG, RAT* >5.0 G/KG, RABBIT* NOT AVAILABLE
* BASED ON API STUDIES
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SECTION III HEALTH INFORMATION
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THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA
HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).
EYE CONTACT: BASED ON COMPONENT INFORMATION PRODUCT IS NO MORE THAN MINIMALLY
IRRITATING TO THE EYES.
SKIN CONTACT: BASED ON COMPONENT INFORMATION PRODUCT IS NO MORE THAN MILDLY
IRRITATING TO THE SKIN. PROLONGED AND REPEATED CONTACT CAN
RESULT IN VARIOUS SKIN DISORDERS SUCH AS DERMATITIS, FOLLICULITIS
OR OIL ACNE.
INHALATION: INHALATION OF VAPORS (GENERATED AT HIGH TEMPERATURES ONLY) OR OIL
MIST FROM THIS PRODUCT MAY CAUSE MILD IRRITATION OF THE UPPER
RESPIRATORY TRACT.
INGESTION: BASED ON COMPONENT INFORMATION THIS PRODUCT IS NO MORE THAN
SLIGHTLY TOXIC IF SWALLOWED.
SIGNS AND SYMPTOMS: IRRITATION AS NOTED ABOVE.
AGGRAVATED MEDICAL CONDITIONS:
PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO
THIS PRODUCT.
OTHER HEALTH EFFECTS:
THIS PRODUCT AND ITS COMPONENTS ARE NOT CLASSIFIED AS CARCINOGENS BY
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), NATIONAL TOXICOLOGY
PROGRAM (NTP) OR OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA).
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SECTION IV OCCUPATIONAL EXPOSURE LIMITS
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COMP OSHA ACGIH
NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL OTHER
--- ------- ----------- ------- -------- -----
P 5 MG/M3* NONE 5 MG/M3* 10 MG/M3* NONE
*OIL MIST, MINERAL
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SECTION V EMERGENCY AND FIRST AID PROCEDURES
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EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET
MEDICAL ATTENTION.
SKIN CONTACT: REMOVE CONTAMINATED CLOTHING AND WIPE EXCESS OFF. WASH WITH SOAP
AND WATER OR A WATERLESS HAND CLEANER FOLLOWED BY SOAP AND WATER.
IF IRRITATION OCCURS, GET MEDICAL ATTENTION.
INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS
DIFFICULT. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. IN GENERAL NO TREATMENT IS NECESSARY
UNLESS LARGE QUANTITIES OF PRODUCT ARE INGESTED. HOWEVER, GET
MEDICAL ADVICE.
NOTE TO PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN HIGH
VISCOSITY, LOW VOLATILITY PRODUCES, I.E., MOST OILS AND
GREASES.
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SECTION VI SUPPLEMENTAL HEALTH INFORMATION
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SUPPLIER OF CHLORINATED PARAFFIN NOTES, "IN THE NATIONAL TOXICOLOGY PROGRAM,
TWO YEAR ONCOGENICITY CHRONIC TOXICITY STUDIES BY GAVAGE WERE CONDUCTED IN RATS
AND MICE ON A MIXTURE OF CHLORINATED PARAFFIN (C23, 43% CHLORINE). THERE WAS
EVIDENCE OF CARCINOGENIC POTENTIAL ONLY FOR MALE MICE EXPOSED TO HIGH DOSES OF
THE CHLORINATED PARAFFIN TESTED. SINCE INGESTION IS AN UNLIKELY ROUTE OF
EXPOSURE TO CHLORINATED PARAFFIN IN THE WORKPLACE AND EXPOSURE BY OTHER ROUTES
IS EXPECTED TO BE VERY LOW, IT IS UNLIKELY ANY CARCINOGENIC POTENTIAL WILL BE
EXPRESSED."
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SECTION VII PHYSICAL DATA
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BOILING POINT (DEG F): SPECFIC GRAVITY (H2O = 1): VAPOR PRESSURE (MM HG):
NOT AVAILABLE 0.9106 <0.1
MELTING POINT (DEG F): SOLUBILITY IN WATER: VAPOR DENSITY (AIR = 1):
0 (POUR POINT) NEGLIGIBLE NOT AVAILABLE
VISCOSITY: 15
(CS @ 212 DEG F)
EVAPORATION RATE (NORMAL BUTYL ACETATE = 1):NOT AVAILABLE
APPEARANCE AND ODOR:DARK AMBER OIL. SLIGHT HYDROCARBON ODOR.
PHYS/CHEM PROPERTIES: SEE ABOVE FOR DETAILS
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SECTION VIII FIRE AND EXPLOSION HAZARDS
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FLASH POINT AND METHOD: 465 DEG F (PMCC)
FLAMMABLE LIMITS/PERCENT VOLUME IN AIR: LOWER: N/AV HIGHER: N/AV
EXTINGUISHING MEDIA:
USE WATE FOG, FOAM, DRY CHEMICAL OR CO2. DO NOT USE A DIRECT STREAM OF
WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER.
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS:
MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE-SPACE
WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND
RUBBER BOOTS), INCLUDING A POSITIVE-PRESSURE NIOSH-APPROVED SELF-CONTAINED
BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NONE IDENTIFIED
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SECTION IX REACTIVITY
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STABLITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR
CONDITIONS AND MATERIALS TO AVOID:
AVOID HEAT, OPEN FLAMES AND OXIDIZING MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION
CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID, LIQUID, PARTICULATES AND
GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION.
CARBON MONOXIDE AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON
COMBUSTION.
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SECTION X EMPLOYEE PROTECTION
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RESPIRATORY PROTECTION:
IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) USE
A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR
1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING
RESPIRATOR FOR ORGANIC VAPORS AND PARTICULATES.
PROTECTIVE CLOTHING
WEAR CHEMICAL RESISTANT GLOVES AND OTHER PROTECTIVE CLOTHING AS REQUIRED TO
MINIMIZE SKIN CONTACT. WEAR SAFETY GOGGLES TO AVOID EYE CONTACT. TEST DATA
FROM PUBLISHED LITERATURE AND/OR GLOVE AND CLOTHING MANUFACTURERS INDICATE
THE BEST PROTECTION IS PROVIDED BY NITRILE GLOVES.
ADDITIONAL PROTECTIVE MEASURES:
NONE IDENTIFIED
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SECTION XI ENVIRONMENTAL PROTECTION
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SPILL OR LEAK PROCEDURES:
MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS JUDGMENT WHEN CLEANING
UP LARGE SPILLS. *** LARGE SPILLS *** WEAR RESPIRATOR AND PROTECTIVE
CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE AND
CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE SALVAGE VESSELS. SOAK
UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIALS;
DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. ***
SMALL SPILLS *** TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY.
_______________________________________________________________________________
SECTION XII SPECIAL PRECAUTIONS
_______________________________________________________________________________
MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES, INCLUDING SHOES,
THAT CANNOT BE DECONTAMINATED. STORE IN A COOL, DRY PLACE WITH ADEQUATE
VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES.
_______________________________________________________________________________
SECTION XIII TRANSPORTATION REQUIREMENTS
_______________________________________________________________________________
DEPARTMENT OF TRANSPORTATION CLASSIFICATION:
NOT HAZARDOUS BY D.O.T. REGULATIONS
DOT PROPER SHIPPING NAME: NOT APPLICABLE
OTHER REQUIREMENTS: NOT APPLICABLE
_______________________________________________________________________________
SECTION XIV OTHER REGULATORY CONTROLS
_______________________________________________________________________________
THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL
SUBSTANCES.
PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT
AMENDMENTS OF 1990): PER 40 CFR PART 82, THIS PRODUCT DOES NOT CONTAIN NOR WAS
IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS II OZONE DEPLETING
SUBSTANCES.
IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA
SHEET (EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS.
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SECTION XV STATE REGULATORY INFORMATION
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THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PROD
UCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE AP
PLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS YO
U SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE.
STATE LISTED COMPONENT CAS NO PERCENT STATE CODE
_______________________________________________________________________________
ACID TREATED HEAVY NAPHTHENIC 64742-18-3 20-30 MA
DISTILLATE
CHLORINATED PARAFFIN 63449-39-8 <1 LA
CA = CALIFORNIA HAZ. SUBST. LIST; CA65 = CALIFORNIA SAFE DRINKING WATER AND
TOXICS ENFORCEMENT ACT LIST; CT = CONNECTICUT TOX. SUBST. LIST; FL = FLORIDA
SUBST. LIST; IL = ILLINOIS TOX. SUBST. LIST; LA = LOUISIANA HAZ. SUBST. LIST;
MA = MASSACHUSETTS SUBST. LIST; ME = MAINE HAZ SUBST. LIST; MN = MINNESOTA HAZ.
SUBST. LIST; NJ = NEW JERSEY HAZ. SUBST. LIST; PA = PENNSYLVANIA HAZ. SUBST.
LIST; RI = RHODE ISLAND HAZ. SUBST. LIST.
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SECTION XVI SPECIAL NOTES
_______________________________________________________________________________
MSDS REVISED IN SECTIONS II, VII, XV, AND EDS SECTIONS I, III, AND IV.
_______________________________________________________________________________
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
EQUIVA SERVICES, LLC.
_______________________________________________________________________________
ENVIRONMENTAL DATA SHEET
EQUILON EDS: 66501E
DIESELMOTIVE 494
TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS
EQUILON ENTERPRISES
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
PRODUCT CODE: 54748
_______________________________________________________________________________
SECTION I PRODUCT COMPOSITION
_______________________________________________________________________________
NO. COMPOSITION CAS PERCENT
===============================================================================
P DIESELMOTIVE 494 MIXTURE 100
1 HYDROTREATED HEAVY NAPHTHENIC DISTILLATE 64742-52-5 50-60
2 ACID TREATED HEAVY NAPHTHENIC DISTILLATE 64742-18-3 20-30
3 HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 5-10
4 ADDITIVES MIXTURE 10-15
5 CHLORINATED PARAFFIN 63449-39-8 <1
_______________________________________________________________________________
SECTION II SARA TITLE III INFORMATION
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NO. EHS RQ EHS TPQ SEC-313 313 CATEGORY 311/312 CATEGORY
(*1) (*2) (*3) (*4) (*5)
===============================================================================
BASED ON THE DATA AVAILABLE THIS PRODUCT IS NOT REGULATED BY SARA,
TITLE III.
_______________________________________________________________________________
*1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*3 = TOXIC CHEMICAL, SEC 313
*4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC
RELEASE INVENTORY FORM
*5 = CATEGORY (FOR AGGREGATE REPORTING REQUIREMENTS UNDER SARA 311, 312)
HEALTH: H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD
H-2 = DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL: P-3 = FIRE HAZARD
P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 = REACTIVE HAZARD
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SECTION III ENVIRONMENTAL RELEASE INFORMATION
_______________________________________________________________________________
THIS PRODUCT IS COVERED BY EPA'S COMPREHENSIVE ENVIRONMENTAL RESPONSE,
COMPENSATION AND LIABILITY ACT (CERCLA) PETROLEUM EXCLUSION. THEREFORE,
RELEASES TO AIR, LAND, OR WATER ARE NOT REPORTABLE UNDER CERCLA
("SUPERFUND"). HOWEVER, UNDER SECTION 311 OF EPA'S CLEAN WATER ACT (CWA),
THIS PRODUCT IS CONSIDERED AN OIL. AS SUCH, SPILLS INTO OR LEADING TO
SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE
CENTER, 800-424-8802.
THIS PRODUCT IS AN OIL UNDER 49 CFR (DOT) PART 130. IF SHIPPED BY RAIL OR
HIGHWAY IN A TANK WITH A CAPACITY OF 3,500 GALLONS OR MORE, IT IS SUBJECT TO
THE REQUIREMENTS OF PART 130. MIXTURE SOLUTIONS IN WHICH THIS PRODUCT IS
PRESENT AT 10% OR MORE MAY ALSO BE SUBJECT TO THIS RULE.
_______________________________________________________________________________
SECTION IV RCRA INFORMATION
_______________________________________________________________________________
IF THIS PRODUCT BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA
CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL REGULATIONS.
_______________________________________________________________________________
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
EQUIVA SERVICES, LLC.
_______________________________________________________________________________
KAREN G. HAYNES
---------------
EQUIVA SERVICES LLC
P.O. BOX 674414
HOUSTON, TX 77267-4414
FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL
(877) 276-7285
FOR EMERGENCY ASSISTANCE PLEASE CALL
EQUIVA SERVICES LLC: (877) 276-7283
CHEMTREC: (800) 424-9300
}