CAROLINA BIOLOGICAL SUPPLY CO -- 1-BUTANOL -- -
===================== Product Identification ===================== Product ID:1-BUTANOL MSDS Date:08/03/1998 FSC:NIIN:Submitter:D DG MSDS Number: CKDCY === Responsible Party === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD City:BURLINGTON State:NC ZIP:27215-3387 Country:US Info Phone Num:800-227-1150 Emergency Phone Num:800-227-1150 Chemtrec Ind/Phone:(800)424-9300 CAGE:59896 === Contractor Identification === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD Box:City:BURLINGTON State:NC ZIP:27215-3387 Country:US Phone:800-227-1150/910-584-0381 Contract Num:MDA414-00-P-1174 CAGE:59896 Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD Box:City:BURLINGTON State:NC ZIP:27215-3387 Country:US Phone:800-227-1150/910-584-0381 Contract Num:MDA414-98-A-0118-0051 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:1-BUTANOL CAS:71-36-3 RTECS #:EO1400000 = Wt:100. OSHA PEL:300 MG/M3;100 PPM ACGIH STEL:C152 MG/M3;C50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 790MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:TARGET ORGANS: EYE, SKIN, KIDNEYS, LIVER, RESPIRATORY SYSTEM. EYES-MAY CAUSE IRRITATION. SKIN-MAY CAUSE IRRITATION. INGESTION-MAY CAUSE GASTROINTESTINAL DISCOMFORT. INHALATION-MAY CAUSE IRRITATION T O RESPIRATORY TRACT. Explanation of Carcinogenicity:NOT LISTED AS CAUSING CANCER BY NTP, IARC, OR OSHA. Medical Cond Aggravated by Exposure:EYE, SKIN, AND RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES, RAISING & LOWERING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN: THOROUGHLY WASH EXPOSED AREA FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMIN ATED CLOTHING BEFORE RESUE. GET MEDICALATTENTION IF IRRITATION PERSISTS. INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE PLENTY OF WATER. IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. KEEP PERSON WARM, QUIET, & GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=35.C, 95.F Autoignition Temp:=342.C, 647.6F Lower Limits:1.4 Upper Limits:11.2 Extinguishing Media:DRY CHEMICAL, CO2 OR APPROPRIATE FOAM. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:VAPOR CAN TRAVEL DISTANCES TO IGNITION SOURCE AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP PERSONNEL SHOULD WEAR PROTECTIVE EQUIPMENT AND CLOTHING. ABSORB MATERIAL WITH SUITABL E ABSORBANT AND CONTAINERIZE FOR DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED IN A COOL AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS EQUIPMENT. Other Precautions:DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR SHOULD BE WORN IF PEL OR TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST: YES. MECHANICAL (GENERAL): YES. Protective Gloves:RUBBER, NEOPRENE, PVC OR EQUIVALENT. Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES AT ALL TIMES. Other Protective Equipment:LAB COAT, EYE WASH, AND SAFETY SHOWER. Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE RESUE. Supplemental Safety and Health PRODUCT CODES: 84-0490; 84-9790; 84-9792; 84-9794 ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=118.C, 244.4F Melt/Freeze Pt:=-89.C, -128.2F Vapor Pres:4 Vapor Density:2.6 Spec Gravity:0.81 Evaporation Rate & Reference:0.46 (BUAC=1) Solubility in Water:MODERATE 1-10% Appearance and Odor:COLORLESS LIQUID WITH AN ALCOHOL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION =================== Toxicological Information =================== Toxicological Information:ORAL-RAT LD50: 790 MG/KG. SKN-RBT LD50: 4200 MG/KG. IHL-HMN TCLO: 25 PPM. ===================== Ecological Information ===================== Ecological:EPA WASTE NUMBERS: U031 (TOXIC WASTE). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. =================== MSDS Transport Information =================== Transport Information:DESCRIPTION: BUTANOLS, 3, UN1120, III. ===================== Regulatory Information ===================== SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312 REPORTING: ACUTE. SARA SECTION 313 CHEMICALS NAME LIST: YES. Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY. CERCLA SEC. 103 RQ (LBS): 5000. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.